Luminescence spectroscopy of matrix-isolated atomic cadmium
نویسندگان
چکیده
منابع مشابه
Luminescence spectroscopy of matrix-isolated z 6P state atomic manganese.
The relaxation of electronically excited atomic manganese isolated in solid rare gas matrices is observed from recorded emission spectra, to be strongly site specific. z 6P state excitation of Mn atoms isolated in the red absorption site in Ar and Kr produces narrow a 4D and a 6D state emissions while blue-site excitation produces z 6P state fluorescence and broadened a 4D and a 6D emissions. M...
متن کاملLuminescence spectroscopy of matrix-isolated atomic manganese: excitation of the "forbidden" a6D(J)<-->a6S transitions.
Laser-induced excitation spectra recorded for the electric-quadrupole 3d(6)4s a6D(J)<--3d(5)4s2a6S(5/2) transitions of atomic Mn, allow assignment of the red emission features, previously observed in Mn/RG (RG=Ar, Kr and Xe) matrices with resonance 3d(5)4s4pz6P(5/2)<--3d(5)4s2 a6S(5/2) excitation, to the metastable a6D(9/2) state. Narrow excitation bands recorded for the red site in the Mn/Kr s...
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A new and simple method followed by atomic absorption spectrometry has been developedfor indirect determination of ascorbic acid (AA). The proposed method was based on the oxidationof AA to dehydroascorbic acid with Cu2+cation(200mgL-1)in an ammonium thiocyanatesolution atpH2.4. AA reduces Cu2+to Cu+followed by the precipitation of Cu+ with SCN-. Then, the excess ofCu2+in the solution was measu...
متن کاملThe absorption and excitation spectroscopy of matrix-isolated atomic manganese: sites of isolation in the solid rare gases.
This study collects information from absorption and luminescence excitation spectra recorded for Mn atoms isolated in the solid rare gases Ar, Kr, and Xe and presents an analysis of the site occupancy, based on the polarizabilities of the rare gases and the observed spectral shifts. Two thermally stable sites of isolation exist for atomic Mn in solid Ar and Kr, while a single thermally stable s...
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Recent infrared spectroscopic results from a new setup for the deposition of mass-selected ions in neon matrices are presented. The strong infrared signal observed for the asymmetric stretch of CNC and the appearance of the corresponding band for CNC in its natural isotopic abundance, demonstrates the sensitivity and usefulness of the apparatus. Evidence of a combination band of CNC involving t...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1999
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.478244